Vestnik KRAUNC. Fiz.-Mat. Nauki. 2022. vol. 38. no. 1. pp. 166–185. ISSN 2079-6641

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MSC 8605

Research Article

Assessment of efficiency of decontamination of oil and gas industry drilling wastes by chemical treatment of sludge samples with solutions of acids and alkalis

A. V. Shumilo¹, G. M. Yessilkanov², G. A. Yakovlev³

¹Tomsk Polytechnic University, 634050, 30 Lenina ave., Tomsk, Russia
²Branch «Institute of Radiation Safety and Ecology» of RSE «NNC RK», 071100, Kurchatov, st. Beybit atom, 2, Kazakhstan
³Tomsk State University, 634050, 36 Lenina ave., Tomsk, Russia

E-mail: artem7@tpu.ru

Currently, a serious potential danger for geosystems of oil fields and the population of territories of settlements of oil and gas production is represented by wastes associated with drilling of oil and gas wells. The greatest part of the drilling cuttings has a mineral origin, and frequently can be radioactive, having in its structure the natural radionuclides which concentrations can reach the levels of RW. This work is experimental in its application and calculation of the effectiveness of methods of chemical decontamination of drill cuttings by acid and alkaline solutions. The results obtained on the basis of the experiment indicate satisfactory effectiveness of such methods for decontamination of mineral materials and are of particular interest in such fields of science as radiation geophysics, geochemistry and radioecology.

Key words: natural radionuclides, drilling wastes, radiation control, sludge deactivation, gamma spectrometry, effective specific activity, radiation safety, oil and gas industry.

DOI: 10.26117/2079-6641-2022-38-1-166-185

Original article submitted: 04.04.2022

Revision submitted: 22.04.2022

For citation. Shumilo A. V., Yessilkanov G. M., Yakovlev G. A. Assessment of efficiency of decontamination of oil and gas industry drilling wastes by chemical treatment of sludge samples with solutions of acids and alkalis. Vestnik KRAUNC. Fiz.-mat. nauki. 2022, 38: 1, 166-185. DOI: 10.26117/2079-6641-2022-38-1-166-185

Competing interests. The authors declare that there are no conflicts of interest regarding authorship and publication.

Contribution and Responsibility. All authors contributed to this article. Authors are solely responsible for providing the final version of the article in print. The final version of the manuscript was approved by all authors.

The content is published under the terms of the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0/deed.ru)

© Shumilo A. V., Yessilkanov G. M., Yakovlev G. A., 2022

References

  1. Programma yadernykh ispytaniy v narodno-khozyaystvennykh tselyakh v SSSR. [Program of Nuclear Tests for National Economic Purposes in the USSR], Electronic resource URL: https://ru.wikipedia.org/wiki список_мирных_ядерных_взрывов_в_СССР (Date of access: 19.02.2022) (in Russian).
  2. Nozik М. L. Nauchno-metodicheskie osnovy obespecheniya radioekologicheskoy bezopasnosti an predpriyatiyakh neftegazovogo kompleksa [Scientific and methodological basis for ensuring radioecological
    safety at oil and gas enterprises]. Moscow: Avtoreferat dissertatsii na soiskanie uchenoy stepeni kandidata geologo-mineralogicheskikh nauk [Author’s thesis for the degree of Candidate of Geological and Mineralogical Sciences], 2010. 24 pp. (in Russian)
  3. Stamat I.P., Lisachenko E.P. Effektivnaya udel’naya aktivnost’ prirodnykh radionuklidov v sredakh s narushennym radioaktivnym ravnovesiem v ryadakh urana i toriya [Effective specific activity of natural radionuclides in environments with disturbed radioactive equilibrium in the series of uranium and thorium],Radiatsionnaya gigiena — Radiation hygiene, 2017. vol. 1, no. 1, pp. 27–31 (in Russian).
  4. Primenenie trebovaniy po proektirovaniyu poligonov razmeshcheniya promyshlennykh otkhodov k shlamovym ambaram. [Application of landfill design requirements for industrial waste to sludge pits], Elektronnyy resurs URL: https://www.normacs.info/answers/4453 (Date of access: 03.03.2022) (in Russian).
  5. Ostakh O. S. Ekologo-ekonomicheskiy potentsial tekhnologiy utilizatsii burovykh shlamov [Environmental and economic potential of drilling cuttings utilization technologies], Dissertatsiya na soiskanie uchenoy stepeni kandidata tekhnicheskikh nauk. Moscow: Federal’noe gosudarstvennoe avtonomnoe obrazovatel’noe uchrezhdenie vysshego obrazovaniya «rossiyskiy gosudarstvennyy universitet nefti i gaza (natsional’nyy issledovatel’skiy universitet) imeni I.M. GUBKINA» [Dissertation for the degree of Candidate of Technical Sciences Gubkin Russian State Oil and Gas University (National Research University) Federal State Autonomous Educational Institution of Higher Education], 2021 (in Russian).
  6. Kislota azotnaya. GOST 4461. Reaktivy Tekhnicheskie usloviya [Nitric acid. GOST 4461. Reagents Technical specifications] (in Russian).
  7. Kislota solyanaya. GOST 3118-77 (ST SEV 4276-83). Reaktivy. Tekhnicheskie usloviya [Hydrochloric acid. GOST 3118-77 (ST SEV 4276-83). Reagents. Technical conditions] (in Russian).
  8. Kislota sernaya. GOST 4204-77 (ST SEV 3856-82). Reaktivy. Tekhnicheskie usloviya [Sulfuric acid. GOST 4204-77 (ST.SEV 3856-82). Reagents. Technical conditions] (in Russian).
  9. Natriya gidrookis’. GOST 4328-77. Reaktivy. Tekhnicheskie usloviya [Sodium hydroxide. GOST 4328-77. Reagents. Technical specifications] (in Russian).
  10. Kaliy khloristyy. GOST 4234-77. Reaktivy. Tekhnicheskie usloviya [Potassium chloride. GOST 4234-77. Reagents. Technical specifications] (in Russian).
  11. Kal’tsiy uglekislyy. GOST 4530-76. Reaktivy. Tekhnicheskie usloviya [Calcium carbonate. GOST 4530-76. Reagents. Technical specifications] (in Russian).
  12. Voda distillirovannaya. GOST R 58144-2018. Tekhnicheskie usloviya [Distilled water. GOST P 58144-2018. Technical specifications] (in Russian).
  13. Shkafy vytyazhnye radiokhimicheskie. GOST 23308-78. (CT SEV 3552-82). Obshchie tekhnicheskie trebovaniya [Radiochemical fume hoods. GOST 23308-78. (CT SEV 3552-82). General technical requirements] (in Russian).
  14. GOST R 51568-99 (ISO 3310-1-90). Tekhnicheskie usloviya [GOST R 51568-99 (ISO 3310-1-90). Technical specifications] (in Russian).
  15. GOST 12.4.269-2014. «Sistema standartov bezopasnosti truda. Sredstva individual’noy zashchity, prednaznachennye dlya rabot s radioaktivnymi veshchestvami, i materialy dlya ikh izgotovleniya. Metody opredeleniya dezaktiviruyushchey sposobnosti rastvorov» [GOST 12.4.269-2014. «System of labor safety standards. Personal protective equipment intended for work with radioactive substances and materials for their manufacture. Methods for determining the decontaminating ability of solutions»] (in Russian).
  16. GOST R 51966-2002. «Radioaktivnoe zagryaznenie. Tekhnicheskie sredstva dezaktivatsii. Obshchie tekhnicheskie trebovaniya» [GOST R 51966-2002. «Radioactive contamination. Technical means of decontamination. General technical requirements»] (in Russian).
  17. PND F 12.13.1-03. Metodicheskie rekomendatsii tekhnika bezopasnosti pri rabote v analiticheskikh laboratoriyakh, (v t.ch. radiologicheskikh) [PND F 12.13.1-03 Methodical recommendations
    for safety at work in analytical laboratories (including radiological)] (in Russian).
  18. «Metodika izmereniya aktivnosti radionuklidov v schetnykh obraztsakh na stsintillyatsionnom gamma-spektrometre s ispol’zovaniem programmnogo obespecheniya «PROGRESS» [«Methods of measuring the activity of radionuclides in counting samples on the scintillation gamma spectrometer using the software «PROGRESS»]. Moscow: State Enterprise VNIIFTRI, 2016 (in Russian).
  19.  «Metodicheskie rekomendatsii po prigotovleniyu schetnykh obraztsov dlya spektrometricheskikh
    kompleksov s programmnym obespecheniem «PROGRESS» [«Methodological recommendations on the preparation of counting samples for spectrometric complexes with the software «PROGRESS»], 2008 (in Russian).
  20. GOST 4517-87. Mezhgosudarstvennyy standart. Reaktivy. «Metody prigotovleniya vspomogatel’nykh reaktivov i rastvorov, primenyaemykh pri analize» [GOST 4517-87. Interstate standard. Reagents. «Methods for the preparation of auxiliary reagents and solutions used in the analysis».] (in Russian).
  21. Gornaya entsiklopediya. Radiy. [Mining Encyclopedia. Radium.], Electronic resource URL: http://www.mining-enc.ru/r/radij/ (Date of access: 28.02.2022) (in Russian).

Shumilo Artem Vasilyevich – Master’s student at the Nuclear-Fuel Cycle Department School of Nuclear Science & Engineering of the National Research Tomsk Polytechnic University, Tomsk, Russia, ORCID 0000-0002-1045-5004.


Yessilkanov Gani Mukhtarovich – Engineer at Elemental Analysis Laboratory, Analytical Research Department, Branch of «Institute of Radiation Safety and Ecology, RSE NNC RK, Kurchatov, Kazakhstan


Yakovlev Grigorii Alekseevich – student at Tomsk State University, Tomsk, Russia, ORCID 0000-0001-7842-5672.


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